Thermal transport and chemical conversion in single reacting sorbent particles

The effects of particle size and carbon dioxide concentration on chemical conversion in engineered spherical particles undergoing calcium oxide looping are investigated. Particles are thermochemically cycled in a furnace under different carbon dioxide concentrations. Changes in composition due to chemical reactions are measured using thermogravimetric analysis. Gas composition at the furnace exit is evaluated with mass spectroscopy. A numerical model of thermal transport phenomena developed previously is adapted to match the physical system investigated in the present study. The model is used to elucidate effects of reacting medium characteristics on particle temperature and reaction extent. Experimental and numerical results show that (1) an increase in particle size results in a decrease in carbonation extent, and (2) the carbonation step consists of fast and slow reaction regimes. The reaction rates in the fast and slow carbonation regimes increase with increasing carbon dioxide concentration. The effect of carbon dioxide concentration and the distinction between the fast and slow regimes become more pronounced with increasing particle size.     

Effects of Winding Attachment Positions on Output Characteristics of Flux‐Modulating Synchronous Machines

The flux‐modulating synchronous machine (FMSM) is a new type of multipole SM with nonoverlapping concentrated armature and field windings on the stator. This paper compares the output characteristics of two FMSMs through finite element analysis (FEA) and experiments. In both of the FMSMs, the attachment positions of the armature and field windings are swapped. To determine the reason for the discrepancies in their output characteristics, unsaturated inductances were calculated using a d‐‐q equivalent circuit. In addition, the calculated results of the inductances were confirmed through a visualization of the leakage fluxes using FEA. The results of the study show that the synchronous inductance can be reduced by attaching the armature winding to the air‐gap side of the stator teeth and that the reduction leads to an increase in output power.     

集中药包与条形药包爆破漏斗及抛掷堆积研究

把集中药包拉成条形药包之后，其爆破漏斗变化有多大?条形药包能否改善抛掷堆积?可否用集中药包的爆破漏斗参数(n、R、R’、P)及经验方法来设计条形药包的爆破漏斗?本试验研究将回答这些问题。     

Preparation of flexible polyhedral particles via concentrated emulsion templating polymerization

This paper presents recent efforts on the preparation of flexible polyhedral particles via concentrated emulsion templating polymerization in which the hydrophilic monomer (acrylamide) and hydrophobic monomer (butyl acrylate) are polymerized simultaneously in the continuous and dispersed phase, respectively. Such templating polymerization has been enhanced in our systems owing to the introduction of acrylamide monomer and their higher polymerization rate in continuous phase as compared with butyl acrylate in dispersed phase. Diffusion between the different phases was also inhibited. Furthermore, the stability of the concentrated emulsion and the molecular weight of the produced poly(butyl acrylate) were found to be significantly affected by the amount of redox initiator. The morphology of the particles could be controlled by varying the volume fraction of the dispersed phase and the polyhedral particles were achieved at higher volume fraction. Copyright © 2005 Society of Chemical Industry     

利用网络技术实施财务集中控制

针对企业集团分权化管理的缺点，设计出一套利用互联网络技术实现企业集团财务集中控制的模式，给出了模式的图示及说明。     

Structural Disruption of Toothpastes Under Deformation — An Easy Release of Active Ingredients

The author suggests a technological approach relevant to the optimization of toothpaste compositions with regard to the easy release of the therapeutic ingredients under shear deformation. It is based on the comparative assessment of the steady‐state viscous behaviour of placebo samples (mixtures containing all the components except the therapeutic ingredients) and the final products. It is presumed that the maximum beneficial effect of the toothpastes, as therapeutic agents, is achieved if the final products and the placebo blends display similar shear‐thinning characteristics.     

Rheological behaviour of concentrated yeast suspension

The effect of yeast cell volumetric concentration on the rheological properties of the suspensions was measured in a pipe-flow viscometer at 30°C: at low microbial concentrations the suspensions were Newtonian; however, non-Newtonian behaviour, which could be described by the power-law equation, was observed with suspensions at high microbial volumetric concentrations. At conditions of constant microbial morphology and growth rate, the results also indicated that a relationship could be developed between the power-law constants and the microbial volumetric concentration.     

集中载荷作用下的套管抗挤能力分析

根据油田套管损坏情况,建立了集中载荷作用下的套管抗挤能力计算模型,利用能量法和曲杆理论,分析研究了承受180°对称分布集中载荷、90°均匀分布集中载荷和120°均匀分布集中载荷下中厚壁套管抗挤能力,得出了理想圆管抗挤强度和套管屈曲临界挤毁压力的计算公式,通过分析比较理论解与有限元解,其最大相对误差不超过1%,得出了套管抵抗局部载荷的能力低于抵抗均布载荷的结论。     

高浓度难降解有机废水湿式氧化可行性研究

选择四种高浓度难降解有机废水,在2L高压间歇反应釜中,研究了湿式氧化效果与技术可行性。结果表明:从氧化的容易程度来看,乳化液废水>丙硫咪唑废水>甲胺磷废水>分散蓝废水;各废水湿式氧化后可生化性得到显著改善;Cu2+有不同程度的催化作用;甲胺磷废水和丙硫咪唑废水对不锈钢反应釜腐蚀严重,乳化液废水最适宜湿式氧化。反应温度显著影响废水湿式氧化效果,温度越高氧化率越高。     

氢溴酸法合成1-溴代十二烷

以生产溴代金刚烷得到的副产品氢溴酸为原料,在浓硫酸存在的条件下与正十二醇进行反应合成1-溴代十二烷。确定优惠合成条件为:n(正十二醇):n(氢溴酸):n(浓硫酸)=1:1.25:1.15,回流时间3h。产品经气相色谱分析证明无副产物,收率92.5%,含量99.9%,产品经IR和折光率进行表征。